Enantioselective Direct Mannich‐Type Reactions Catalyzed by Frustrated Lewis Acid/Brønsted Base Complexes. (22nd September 2017)
- Record Type:
- Journal Article
- Title:
- Enantioselective Direct Mannich‐Type Reactions Catalyzed by Frustrated Lewis Acid/Brønsted Base Complexes. (22nd September 2017)
- Main Title:
- Enantioselective Direct Mannich‐Type Reactions Catalyzed by Frustrated Lewis Acid/Brønsted Base Complexes
- Authors:
- Shang, Ming
Cao, Min
Wang, Qifan
Wasa, Masayuki - Abstract:
- Abstract: An enantioselective direct Mannich‐type reaction catalyzed by a sterically frustrated Lewis acid/Brønsted base complex is disclosed. Cooperative functioning of the chiral Lewis acid and achiral Brønsted base components gives rise to in situ enolate generation from monocarbonyl compounds. Subsequent reaction with hydrogen‐bond‐activated aldimines delivers β‐aminocarbonyl compounds with high enantiomeric purity.
- Is Part Of:
- Angewandte Chemie. Volume 129:Number 43(2017)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 129:Number 43(2017)
- Issue Display:
- Volume 129, Issue 43 (2017)
- Year:
- 2017
- Volume:
- 129
- Issue:
- 43
- Issue Sort Value:
- 2017-0129-0043-0000
- Page Start:
- 13523
- Page End:
- 13526
- Publication Date:
- 2017-09-22
- Subjects:
- Bor -- Frustrierte Lewis-Paare -- Lewis-Säuren -- Mannich-Reaktionen -- Säure-Base-Katalyse
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201708103 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 14503.xml