Nano-structured LSM-YSZ refined with PdO/ZrO2 oxygen electrode for intermediate temperature reversible solid oxide cells. (31st July 2020)

• Record Type: Journal Article
• Authors: Tan, Yuan; Gao, Shu; Xiong, ChunYan; Chi, Bo
• Is Part Of: International journal of hydrogen energy. Volume 45:Number 38(2020)
• Page Start: 19823
• Page End: 19830
• Publication Date: 2020-07-31
• Subjects: Palladium oxide -- Zirconia -- Oxygen electrode -- Reversible solid oxide cells -- Impregnation; Hydrogen as fuel -- Periodicals; Hydrogène (Combustible) -- Périodiques; Hydrogen as fuel; Periodicals; 665.81
• DOI: 10.1016/j.ijhydene.2020.05.116
• Languages: English
• ISSNs: 0360-3199

Abstract

Abstract: To promote the application of traditional (La0.8 Sr0.2 )0.95 MnO3-δ -YSZ (LSM-YSZ) oxygen electrodes to both solid oxide fuel cells (SOFCs) and solid oxide electrolysis cells (SOECs) modes at intermediate temperatures, we select PdO as the catalyst and ZrO2 as the PdO stabilizer to decorate the LSM-YSZ. The high active PdO particles enhance the electrocatalytic activity, and stable ZrO2 can hinder the growth and agglomeration of the PdO particles. PdO and ZrO2 are co-impregnated into the LSM-YSZ to form a nano-structured PdO/ZrO2 -LSM-YSZ composite electrode. At 750 °C, the obtained cell attains a power density peak of 1.114 W cm −2 in SOFC mode and shows significant improvement of the cell with LSM-YSZ composite oxygen electrode. As a SOEC, when the water content is 90 vol%AH (absolute humidity) at the hydrogen electrode, the cell exhibits an extraordinary current density of 2.322 A cm −2 under applied voltage of 2.0 V at 750 °C. Moreover, the cell shows notable long-term stability during water electrolysis. Therefore, this study demonstrates that the nano-structured PdO/ZrO2 -LSM-YSZ based material as a high active and stable oxygen electrode can greatly promote the application of LSM-YSZ electrode in reversible solid oxide electrolysis cell (RSOCs) field. Highlights: PdO and ZrO2 co-impregnated LSM-YSZ oxygen electrode is investigated. A power density peak of 1.114 W cm −2 can be obtained in SOFC mode. The cell achieves a high hydrogen production of 971 mL cm −2 h −1 as a SOEC. The ZrO2 particles as the stabilizer of PdO greatly improve the stability.