Template Synthesis, Metalation, and Self‐Assembly of Protic Gold(I)/(NHC)2 Tectons Driven by Metallophilic Interactions. (6th June 2016)
- Record Type:
- Journal Article
- Title:
- Template Synthesis, Metalation, and Self‐Assembly of Protic Gold(I)/(NHC)2 Tectons Driven by Metallophilic Interactions. (6th June 2016)
- Main Title:
- Template Synthesis, Metalation, and Self‐Assembly of Protic Gold(I)/(NHC)2 Tectons Driven by Metallophilic Interactions
- Authors:
- Ruiz, Javier
García, Lucía
Sol, Daniel
Vivanco, Marilín - Abstract:
- Abstract: A new protocol for the synthesis of protic bis(N‐heterocyclic carbene) complexes of Au I by a stepwise metal‐controlled coupling of isocyanide and propargylamine is described. They are used as tectons for the construction of supramolecular architectures through metalation and self‐assembly. Notably a unique polymeric chain of Cu I with alternate Au I /bis(imidazolate) bridging scaffolds and strong unsupported Cu I –Cu I interactions has been generated, as well as a 28‐metal‐atoms cluster containing a nanopiece of Cu2 O trapped by peripheral Au I /bis(imidazolate) moieties.
- Is Part Of:
- Angewandte Chemie. Volume 128:Number 29(2016)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 128:Number 29(2016)
- Issue Display:
- Volume 128, Issue 29 (2016)
- Year:
- 2016
- Volume:
- 128
- Issue:
- 29
- Issue Sort Value:
- 2016-0128-0029-0000
- Page Start:
- 8526
- Page End:
- 8530
- Publication Date:
- 2016-06-06
- Subjects:
- Gold -- Heterometallkomplexe -- Kupfer -- N-heterocyclische Carbene -- Selbstorganisation
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201603688 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 14475.xml