Highly active and selective photochemical reduction of CO2 to CO using molecular-defined cyclopentadienone iron complexes. Issue 54 (15th June 2016)
- Record Type:
- Journal Article
- Title:
- Highly active and selective photochemical reduction of CO2 to CO using molecular-defined cyclopentadienone iron complexes. Issue 54 (15th June 2016)
- Main Title:
- Highly active and selective photochemical reduction of CO2 to CO using molecular-defined cyclopentadienone iron complexes
- Authors:
- Rosas-Hernández, Alonso
Alsabeh, Pamela G.
Barsch, Enrico
Junge, Hernrik
Ludwig, Ralf
Beller, Matthias - Abstract:
- Abstract : Highly active and selective visible-light-driven CO2 reduction to CO catalyzed by well-defined cyclopentadienone iron complexes. Abstract : Herein, we report highly active (cyclopentadienone)iron–tricarbonyl complexes for CO2 photoreduction using visible light with an Ir complex as photosensitizer and TEOA as electron/proton donor. Turnover numbers (TON) of ca. 600 (1 h) with initial turnover frequencies (TOF) up to 22.2 min −1 were observed. Operando FTIR measurements allowed for the proposal of a plausible mechanism for catalyst activation.
- Is Part Of:
- Chemical communications. Volume 52:Issue 54(2016)
- Journal:
- Chemical communications
- Issue:
- Volume 52:Issue 54(2016)
- Issue Display:
- Volume 52, Issue 54 (2016)
- Year:
- 2016
- Volume:
- 52
- Issue:
- 54
- Issue Sort Value:
- 2016-0052-0054-0000
- Page Start:
- 8393
- Page End:
- 8396
- Publication Date:
- 2016-06-15
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c6cc01671e ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 14463.xml