Effects of Lithium Bis(fluorosulfonyl)imide Concentration on Performances of Lithium-ion Batteries Containing Sulfolane-based Electrolytes. Issue 11 (24th July 2020)

• Record Type: Journal Article
• Authors: Hirata, Kazuhisa; Morita, Yoshihiro; Kawase, Takeo; Sumida, Yasutaka
• Is Part Of: Journal of the Electrochemical Society. Volume 167:Issue 11(2020)
• Publication Date: 2020-07-24
• Subjects: Batteries Li-ion -- Energy Storage -- Batteries - Lithium; Electrochemistry -- Periodicals; 541.3705
• DOI: 10.1149/1945-7111/aba5d6
• Languages: English
• ISSNs: 0013-4651

Abstract

Abstract : Carbonate-free electrolytes based on lithium bis(fluorosulfonyl)imide (LiFSI) and sulfolane (SL) (LiFSI/SL) are promising alternatives to conventional electrolytes based on lithium hexafluorophosphate and ethylene carbonate. In this study, we show the effects of LiFSI concentration on performances of LiCoO2 /graphite full cells with LiFSI/SL (1–2.25 mol dm −3 ). The LiFSI/SL electrolytes behave as ideal Walden electrolytes. Cells containing LiFSI/SL with various concentrations exhibit excellent cycle stabilities regardless of their concentrations though they have free-state solvent molecules. Furthermore, the cells containing LiFSI/SL with higher LiFSI concentrations show superior high-rate performances with high discharge capacities and discharge voltages due to high lithium dissociation and lithium ion transference number. The cell containing 1.5 mol dm −3 LiFSI/SL specifically shows excellent low-temperature performance with high discharge capacity and discharge voltage. The low-temperature performance is ascribed from non-crystallinity of the electrolyte as well as the high lithium dissociation.