Role of Polyvinylpyrrolidone (PVP) on Controlling the Structural, Optical, and Electrical Properties of Vanadium Pentoxide (V2O5) Nanoparticles. Issue 37 (1st October 2020)

• Record Type: Journal Article
• Authors: Neupane, Ganga R.; Hari, Parameswar
• Is Part Of: ChemistrySelect. Volume 5:Issue 37(2020)
• Page Start: 11596
• Page End: 11607
• Publication Date: 2020-10-01
• Subjects: Nanoparticles -- Polymers -- Impedance spectroscopy -- Resistivity -- Temperature coefficient of resistance.; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/slct.202002916
• Languages: English
• ISSNs: 2365-6549

Abstract

Abstract: Different molar concentrations (0.05–0.2 M) of vanadium pentoxide nanoparticles were synthesized with and without polyvinylpyrrolidone (PVP) using hydrothermal method. The growth mechanism with different molar concentrations as well as the effect of PVP on the structural, optical, and electrical properties have been investigated. The size of the particles was measured from transmission electron microscopy (TEM) and x‐ray diffraction spectroscopy (XRD). Optical properties were analyzed through photoluminescence and absorption measurement. The electrical transport properties were analyzed by impedance spectroscopy and Van der Pauw method. From impedance measurements, dominance of grain boundary resistance over grain resistance was observed. The resistivity also decreased with increasing molar concentrations of nanoparticles with and without PVP. The highest temperature coefficient of resistance (TCR) value of −2.33 %/K with the lowest resistivity of 0.02 Ω. cm for V2 O5 nanoparticle of 0.2 M concentration without using PVP was observed. Therefore, such V2 O5 nanoparticles are a potential material for microbolometer applications. Abstract : Different molar concentration (0.05 M–0.20 M) of vanadium pentoxide nanoparticles (V2 O5 ) with and without the use of polymer (PVP) was synthesized and characterized. Nanoparticles were coated in a glass substrate and heat was supplied for the resistance measurement. This study identifies the higher temperature of coefficient (TCR) and low resistivity values for V2 O5 nanoparticles, which could be applicable for micro bolometer applications.