Cu(i)/sucrose-catalyzed hydroxylation of arenes in water: the dual role of sucrose. Issue 39 (29th September 2020)

• Record Type: Journal Article
• Authors: Watanabe, Kohei; Takagi, Mio; Watanabe, Ayako; Murata, Shigeo; Takita, Ryo
• Is Part Of: Organic & biomolecular chemistry. Volume 18:Issue 39(2020)
• Page Start: 7827
• Page End: 7831
• Publication Date: 2020-09-29
• Subjects: Chemistry, Organic -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1039/d0ob01683g
• Languages: English
• ISSNs: 1477-0520

Abstract

Abstract : Copper(i )/sucrose-catalyzed hydroxylation of aryl halides in neat water has been developed. The dual role of sucrose, the reaction pathway, and the high selectivity were investigated using a combination of experimental and theoretical techniques. Abstract : A protocol for the hydroxylation of aryl halides catalyzed by copper(i ) and sucrose in neat water has been developed. The dual role of sucrose, the reaction pathway, and the high selectivity for hydroxylation were investigated using a combination of experimental and theoretical techniques.