Synthesis of non-toxic inorganic blue pigments in the melilite-type structure. Issue 7 (14th September 2020)

• Record Type: Journal Article
• Authors: Gramm, Georg; Fuhrmann, Gerda; Ploner, Kevin; Penner, Simon; Huppertz, Hubert
• Is Part Of: Materials advances. Volume 1:Issue 7(2020)
• Page Start: 2293
• Page End: 2299
• Publication Date: 2020-09-14
• Subjects: 620.11
• DOI: 10.1039/d0ma00541j
• Languages: English
• ISSNs: 2633-5409

Abstract

Abstract : The substitution series of environmentally benign blue pigments with the formula Sr2 Mg1− x Mn x Ge2− y Si y O7 +δ (0 ≤ x ≤ 1; 0 ≤ y ≤ 2) show intensive blue colors, which makes them promising alternatives to popular blue pigments. Abstract : A series of novel melilite-type structured compounds of the general formula Sr2 Mg1− x Mn x Ge2− y Si y O7 +δ (0 ≤ x ≤ 1; 0 ≤ y ≤ 2) was produced by conventional solid-state syntheses and subsequently characterized by X-ray powder diffraction (XRPD) and Rietveld analysis. All prepared compounds crystallize in the tetragonal space group P 4̄21 m with the unit cell dimensions varying dependent on the elements contained in the structure. The diffuse reflectance spectra of the obtained powders were recorded, and the color properties were determined by means of the CIE 1976 L * a * b * color coordinates. With the aim of developing new, non-toxic inorganic blue materials that might be of interest for industrial applications, the expensive element Ge was substituted with Si, while the Mg to Mn ratio was simultaneously varied for color optimization. XPS measurements provided evidence that the blue color displayed by some of the candidates in the melilite-type structure is attributable to the presence of the manganese in a mixed oxidation state of 2+/3+. Finally, the highest blue color value was achieved for Sr2 Mg0.2 Mn0.8 Si2 O7 +δ with b * = −31.3, a remarkable value for an environmentally safe inorganic blue pigment.