Reversible barocaloric effects over a large temperature span in fullerite C60. Issue 39 (28th August 2020)

• Record Type: Journal Article
• Authors: Li, Junning; Dunstan, David; Lou, Xiaojie; Planes, Antoni; Mañosa, Lluís; Barrio, María; Tamarit, Josep-Lluís; Lloveras, Pol
• Is Part Of: Journal of materials chemistry. Volume 8:Issue 39(2020)
• Page Start: 20354
• Page End: 20362
• Publication Date: 2020-08-28
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d0ta05399f
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : Giant reversible barocaloric effects at low pressures in a wide temperature span near room temperature in C60 for solid-state cooling. Abstract : Solid-state cooling methods based on field-driven first-order phase transitions are often limited by significant hysteresis and small temperature span, which increase the input work required to drive the cooling cycle reversibly and reduce the temperature range of operation. Here we show that giant reversible caloric effects can be driven using low hydrostatic pressures in the molecular crystal of fullerene C60 across its order–disorder first-order phase transition due to a small transition hysteresis and a high sensitivity of the transition to pressure. In particular, we obtain isothermal entropy changes Δ S = 25 J K −1 kg −1 under reversible application and removal of a pressure as low as p = 0.05 GPa. We also demonstrate that these features allow us to obtain these giant effects in a wide temperature span around room temperature which, furthermore, is desirable for single-component regenerative coolers. For a pressure change of p = 0.41 GPa, we obtain giant reversible values of Δ S = 31 J K −1 kg −1 and Δ T = 11 K, in a temperature interval larger than 50 K. This very good barocaloric performance postulates C60 as one of the best candidates known so far to be considered by engineers for the development of barocaloric devices. The physics underlying these caloric effects is also analyzed.