Synthesis of Ni3S2 catalysts using various sulphur sources and their HER and OER performances. Issue 39 (17th September 2020)

• Record Type: Journal Article
• Authors: Lv, Xiaowei; Kannan, Palanisamy; Ji, Shan; Wang, Xuyun; Wang, Hui
• Is Part Of: CrystEngComm. Volume 22:Issue 39(2020)
• Page Start: 6517
• Page End: 6528
• Publication Date: 2020-09-17
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/d0ce01015d
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : The performance of nickel sulfur catalyst for HER and OER was affected by its structure resulted from the different sulfur sources. Abstract : It is highly anticipated that hydrogen can be produced via water splitting, and can be electrocatalyzed using non-precious electrocatalysts. Accordingly, nickel sulfide (Ni3 S2 ) has attracted considerable attention due to its high electrochemical performance for the hydrogen evolution reaction and oxygen evolution reaction. In this study, nano-sized Ni3 S2 binder-free electrodes were directly grown on Ni foam using various methods. The obtained results showed that the interconnected sheet-like Ni3 S2 with a hydrophilic surface, which was prepared from Na2 S via the hydrothermal method, exhibited the best HER and OER electrocatalytic performance. Its thin nanosheet structure could offer more active centers for the HER and OER in the aqueous alkaline electrolyte and its hydrophilic surface could also facilitate the transfer of ions at the interface of the electrode and electrolyte. The best Ni3 S2 electrode synthesized using Na2 S exhibited an overpotential of 43 mV and 127 mV at the current density of 10 mA cm −2 and 100 mA cm −2, respectively. Furthermore, it also exhibited superior electrochemical activity and durability for the OER.