Carbonylative cycloaddition between two different alkenes enabled by reactive directing groups: expedited construction of bridged polycyclic skeletons. Issue 81 (11th September 2020)

• Record Type: Journal Article
• Authors: Gao, Bingjian; Zou, Suchen; Yang, Guoqing; Ding, Yongzheng; Huang, Hanmin
• Is Part Of: Chemical communications. Volume 56:Issue 81(2020)
• Page Start: 12198
• Page End: 12201
• Publication Date: 2020-09-11
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d0cc05362g
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A novel palladium-catalyzed highly selective hydrocarbonylative cycloaddition reaction with two different alkenes in the presence of CO enabled by a reactive directing-group is developed, which offers efficient access to bicyclo[2, 2, 2]lactones. Abstract : A novel palladium-catalyzed highly selective hydrocarbonylative cycloaddition reaction with two different alkenes in the presence of CO enabled by a reactive directing-group is developed, which offers efficient and convenient access to lactone-containing bridged polycyclic compounds in high yield with high chemo- and stereoselectivities.