Highly photoemissive polymer–transition metal complexes based on poly(2‐hydroxyethyl) methacrylate. Issue 11 (31st October 2019)

• Record Type: Journal Article
• Authors: Stan, Corneliu S; Coroaba, Adina; Popa, Marcel; Ursu, Laura E
• Is Part Of: Polymer international. Volume 69:Issue 11(2020)
• Page Start: 1081
• Page End: 1088
• Publication Date: 2019-10-31
• Subjects: lanthanide complexes -- photoemissive polymer complexes -- luminescent polymers; Plastics -- Periodicals; Polymers -- Periodicals; Polymerization -- Periodicals; 547.7
• DOI: 10.1002/pi.5926
• Languages: English
• ISSNs: 0959-8103

Abstract

Abstract: The paper presents several new polymer complexes based on poly(2‐hydroxyethyl) methacrylate (P‐HEMA) and transition metals including Y 3+, Eu 3+, Tb 3+ and Dy 3+ . Red‐, green‐, blue‐ and yellow‐emitting polymer complexes with remarkable photoluminescent (PL) properties, high degree of transparency and excellent processability both in bulk and in thin film were prepared and investigated. In the case of the prepared P‐HEMA–Eu 3+ and P‐HEMA–Tb 3+ polymer complexes, divinylbenzene was used as a crosslinker resulting a markedly enhanced PL emission, most probably due to the presence of the benzene rings which improve the efficiency of the energy transfer to the cation emissive centres. The prepared polymer complexes were structurally investigated through Fourier transform infrared and X‐ray photoelectron spectroscopies while atomic force microscopy was used to study the morphology of the prepared thin films. Steady‐state fluorescence spectroscopy and absolute PL quantum yield were used for the investigation of the luminescent properties. The impressive PL emission and the convenience of preparation in bulk or thin films could be important arguments for a wide area of applications ranging from photonic conversion materials in optoelectronic devices (light‐emitting diodes, flat‐panel displays) to full‐colour watermarks on special‐purpose papers or PL inks and coatings. © 2019 Society of Chemical Industry Abstract : New polymer complexes based on Poly(2‐hydroxy ethyl) methacrylate (P‐HEMA) and transition metals including Y 3+, Eu 3+, Tb 3+, Dy 3+ were obtained. Red, green, blue and yellow emitting polymer complexes with remarkable photoluminescent properties, high transparency degree and excellent processability both in bulk and thin film were investigated.