Through-bottle whisky sensing and classification using Raman spectroscopy in an axicon-based backscattering configuration. Issue 37 (4th September 2020)

• Record Type: Journal Article
• Authors: Fleming, Holly; Chen, Mingzhou; Bruce, Graham D.; Dholakia, Kishan
• Is Part Of: Analytical methods. Volume 12:Issue 37(2020)
• Page Start: 4572
• Page End: 4578
• Publication Date: 2020-09-04
• Subjects: Chemistry, Analytic -- Periodicals; Analytical biochemistry -- Periodicals; Chemical laboratories -- Standards -- Periodicals; 543.1905
• DOI: 10.1039/d0ay01101k
• Languages: English
• ISSNs: 1759-9660

Abstract

Abstract : A novel optical design allows through-bottle Raman spectroscopy of alcohols with minimised glass contributions to the signal, by using a shaped laser beam which forms a ring on the glass and a focus within the contents. Abstract : Non-intrusive detection systems have the potential to characterise materials through various transparent glass and plastic containers. Food and drink adulteration is increasingly problematic, representing a serious health risk as well as an economic issue. This is of particular concern for alcoholic spirits such as Scotch whisky which are often targeted for fraudulent activity. We have developed a Raman system with a novel geometry of excitation and collection, exploiting the beam propagation from an axicon lens, which results in an annular beam at the bottle surface before focusing within the sample. This facilitates the efficient acquisition of Raman signals from the alcoholic spirit contained inside the bottle, while avoiding the collection of auto-fluorescence signals generated by the bottle wall. Therefore, this technique provides a way of non-destructive and non-contact detection to precisely analyse the contents without the requirement to open the bottle.