When Ultimate Adhesive Mechanism Meets Ultimate Anti‐Fouling Surfaces—Polydopamine Versus SLIPS: Which One Prevails?. Issue 18 (7th August 2020)

• Record Type: Journal Article
• Authors: Prieto‐López, Lizbeth Ofelia; Herbeck‐Engel, Petra; Yang, Li; Wu, Qian; Li, Juntang; Cui, Jiaxi
• Is Part Of: Advanced materials interfaces. Volume 7:Issue 18(2020)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2020-08-07
• Subjects: fouling -- penetration -- polydimethylsiloxane -- polydopamine -- slippery surfaces; Materials science -- Periodicals; 620.11
• DOI: 10.1002/admi.202000876
• Languages: English
• ISSNs: 2196-7350

Abstract

Abstract: What happens when the extremely adhesive and versatile chemistry of polydopamine (PDA) is in contact with the extremely slippery surfaces known as slippery liquid‐infused porous substrates (SLIPS)? Inspired by the pitcher plant, SLIPS possess excellent repellence against a variety of complex liquids and have been proposed as promising antifouling surfaces because of their successful performance even in marine environments. In the counterpart, inspired by the adhesive proteins enabling the strong adhesion of mussels to multiple substrates, PDA has been extensively studied for its ability to adhere on nearly every type of substrate. The interaction between various SLIPS systems and the highly fouling medium from the oxidative polymerization of dopamine is explored here. A PDA coating is observed on all the SLIPS evaluated, modifying their hydrophobicity in most cases. In‐depth study of silicone‐based SLIPS shows that hydrophobicity of PDA coated SLIPS partially recovers with time due to percolation of the lubricant through the coating. "Strongly" bound PDA species are attributed to the formation of dopamine‐polydimethylsiloxane species on the crosslinked matrix, rendering a coating that withstands repeated washing steps in various solvents including water, hexane, and toluene. The results not only satisfy scientific curiosity but also imply a strategy to modify/bond SLIPS. Abstract : This contribution discusses the interaction between two highly investigated functional coatings with extreme opposite properties: one with excellent universal repellence properties known as SLIPS and the extremely fouling coating produced by the oxidative polymerization of dopamine. The polydopamine coating that forms on the silicone‐based SLIPS system after certain exposure to the fouling solution is studied in depth.