Cooperativity within the catalyst: alkoxyamide as a catalyst for bromocyclization and bromination of (hetero)aromatics. Issue 77 (28th August 2020)

• Record Type: Journal Article
• Authors: Mondal, Haripriyo; Sk, Md Raja; Maji, Modhu Sudan
• Is Part Of: Chemical communications. Volume 56:Issue 77(2020)
• Page Start: 11501
• Page End: 11504
• Publication Date: 2020-08-28
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d0cc04673f
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Alkoxyamide has been reported as a catalyst for the activation of N -bromosuccinimide to perform bromocyclization and bromination of a wide range of substrates in a lipophilic solvent with adequate suppression of the background reactions. Abstract : Alkoxyamide has been reported as a catalyst for the activation of N -bromosuccinimide to perform bromocyclization and bromination of a wide range of substrates in a lipophilic solvent, where adequate suppression of the background reactions was observed. The key feature of the active site is the alkoxy group attached to the sulfonamide moiety, which facilitates the acceptance as well as the delivery of bromonium species from the bromine source to the substrates.