Characterization of plasma and gas-phase chemistry during boron-nitride nanomaterial synthesis by laser-ablation of boron-rich targets. Issue 36 (11th September 2020)

• Record Type: Journal Article
• Authors: Yatom, Shurik; Raitses, Yevgeny
• Is Part Of: Physical chemistry chemical physics. Volume 22:Issue 36(2020)
• Page Start: 20837
• Page End: 20850
• Publication Date: 2020-09-11
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/d0cp02890h
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : Formation of B2 N molecules occurs when solid BN is utilized as feedstock for the synthesis of boron nitride nanomaterials. Abstract : In this work, solid targets made from boron and boron nitride (BN) materials are ablated by a nanosecond pulsed laser at sub-atmospheric pressures of nitrogen and helium gases. The excited species in the ablation plume from the target are probed by spatiotemporally resolved optical emission spectroscopy (OES). The evaluation of the chemical composition of the plasma plume revealed that for both boron-rich targets, emission from BN molecules is always observed in nitrogen-rich environments. In addition, BN molecules are also present when ablating a boron nitride target in a helium gas environment, an indication that BN molecules in the plume may originate from the solid target. Furthermore, the ablation of the BN target features emission of B2 N molecules, regardless of the pressure and surrounding gas. These results suggest that the ablation of the BN target is more favorable for the generation of complex molecules containing boron and nitrogen species and possibly hint that BN is also more favorable feedstock for high-yield BN nanomaterial synthesis. Plasma parameters such as the electron temperature (peak value of 1.3 eV) and density (peak value of 2 × 10 18 cm −3 ) were also investigated in this work in order to discuss the chemical dynamics in the plume.