[Cp*RuPb11]3− and [Cu@Cp*RuPb11]2−: centered and non-centered transition-metal substituted zintl icosahedra. Issue 74 (13th August 2020)

• Record Type: Journal Article
• Authors: Li, Ai-Min; Wang, Yi; Zavalij, Peter Y.; Chen, Fu; Muñoz-Castro, Alvaro; Eichhorn, Bryan W.
• Is Part Of: Chemical communications. Volume 56:Issue 74(2020)
• Page Start: 10859
• Page End: 10862
• Publication Date: 2020-08-13
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d0cc03656k
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Cluster anions [Cp*RuPb11 ] 3− (1 ) and [Cu@Cp*RuPb11 ] 2− (2 ) represent the first vertex-substituted zintl icosahedra and 1 is the first non-centered zintl icosahedron isolated in the condensed phase. Abstract : Cluster anions [Cp*RuPb11 ] 3− (1 ) and [Cu@Cp*RuPb11 ] 2− (2 ) represent the first vertex-substituted zintl icosahedra and 1 is the first non-centered zintl icosahedron isolated in the condensed phase. Complexes 1 and 2 are both 12-vertex, 26-electron closo -clusters with C 5v point symmetry and are static on the 207 Pb NMR time scale in solution.