Synthesis of CeOx‐Decorated Pd/C Catalysts by Controlled Surface Reactions for Hydrogen Oxidation in Anion Exchange Membrane Fuel Cells. (23rd July 2020)

• Record Type: Journal Article
• Authors: Singh, Ramesh K.; Davydova, Elena S.; Douglin, John; Godoy, Andres O.; Tan, Haiyan; Bellini, Marco; Allen, Bryan J.; Jankovic, Jasna; Miller, Hamish A.; Alba‐Rubio, Ana C.; Dekel, Dario R.
• Is Part Of: Advanced functional materials. Volume 30:Number 38(2020)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2020-07-23
• Subjects: anion exchange membrane fuel cells -- controlled surface reactions -- electrocatalysts -- hydrogen oxidation reaction -- palladium‐ceria; Materials -- Periodicals; Chemical vapor deposition -- Periodicals; 620.11
• DOI: 10.1002/adfm.202002087
• Languages: English
• ISSNs: 1616-301X

Abstract

Abstract: Due to the sluggish kinetics of the hydrogen oxidation reaction (HOR) in alkaline electrolytes, the development of more efficient HOR catalysts is essential for the next generation of anion‐exchange membrane fuel cells (AEMFCs). In this work, CeO x is selectively deposited onto carbon‐supported Pd nanoparticles by controlled surface reactions, aiming to enhance the homogenous distribution of CeO x and its preferential attachment to Pd nanoparticles, to achieve highly active CeO x ‐Pd/C catalysts. The catalysts are characterized by inductively coupled plasma–atomic emission spectroscopy, X‐ray diffraction, high‐resolution transmission electron microscopy, scanning transmission electron microscopy (STEM), electron energy loss spectroscopy, and X‐ray photoelectron spectroscopy to confirm the bulk composition, phases present, morphology, elemental mapping, local oxidation, and surface chemical states, respectively. The intimate contact between Pd and CeO x is shown through high‐resolution STEM maps. The oxophilic nature of CeO x and its effect on Pd are probed by CO stripping. The interfacial contact area between CeO x and Pd nanoparticles is calculated for the first time and correlated to the electrochemical performance of the CeO x ‐Pd/C catalysts. Highest recorded HOR specific exchange current (51.5 mA mg −1 Pd ) and H2 –O2 AEMFC performance (peak power density of 1, 169 mW cm −2 mgPd −1 ) are obtained with a CeO x ‐Pd/C catalyst with Ce0.38 /Pd bulk atomic ratio. Abstract : This contribution presents a novel approach to synthesize highly active CeO x ‐Pd/C catalysts by controlled surface reactions for intimate contact between CeO x and Pd nanoparticles. The hydrogen oxidation reaction activity is directly correlated to the interfacial contact area between CeO x and Pd. This catalyst shows the highest HOR activity and a record high in operando anion‐exchange membrane fuel cells performance.