Spin crossover modulation in a coordination polymer with the redox-active bis-pyridyltetrathiafulvalene (py2TTF) ligand. Issue 72 (7th August 2020)

• Record Type: Journal Article
• Authors: Zappe, Lisa; Schönfeld, Sophie; Hörner, Gerald; Zenere, Katrina A.; Leong, Chanel F.; Kepert, Cameron J.; D'Alessandro, Deanna M.; Weber, Birgit; Neville, Suzanne M.
• Is Part Of: Chemical communications. Volume 56:Issue 72(2020)
• Page Start: 10469
• Page End: 10472
• Publication Date: 2020-08-07
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/d0cc03788e
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A 1-D chain CP with both SCO and redox activity has been successfully prepared by the combination of a bis-pyridyl functionalised TTF core and a Schiff base-like N2 O2 ligand. Abstract : A one-dimensional Fe II coordination polymer (CP) has been formed which includes the redox-active ligand bis-pyridyltetrathiafulvalene (py2 TTF) and a Schiff base-like N2 O2 ligand. This CP is both spin crossover (SCO) and redox-active in the solid-state, and chemical oxidation results in SCO modification.