A Comprehensive Approach toward Stable Lithium–Sulfur Batteries with High Volumetric Energy Density. Issue 6 (18th November 2016)

• Record Type: Journal Article
• Authors: Pang, Quan; Liang, Xiao; Kwok, Chun Yuen; Kulisch, Joern; Nazar, Linda F.
• Is Part Of: Advanced energy materials. Volume 7:Issue 6(2017)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2016-11-18
• Subjects: carbon nitride‐graphene hybrid -- cross‐linked binder -- lithium–sulfur batteries -- low electrolyte/sulfur ratio -- polysulfide chemisorption; Energy harvesting -- Materials -- Periodicals; Energy conversion -- Materials -- Periodicals; Energy storage -- Materials -- Periodicals; Photovoltaics -- Periodicals; Fuel cells -- Periodicals; Thermoelectric materials -- Periodicals; 621.31
• DOI: 10.1002/aenm.201601630
• Languages: English
• ISSNs: 1614-6832

Abstract

Abstract : A comprehensive approach is reported to construct stable and high volumetric energy density lithium–sulfur batteries, by coupling a multifunctional and hierarchically structured sulfur composite with an in‐situ cross‐linked binder. Through a combination of first‐principles calculations and experimental studies, it is demonstrated that a hybrid sulfur host composed by alternately stacking graphene and layered graphitic carbon nitride embraces high electronic conductivity as well as high polysulfide adsorptivity. It is further shown that the cross‐linked elastomeric binder empowers the hierarchical sulfur composites—multi‐microns in size—with the ability to form crack‐free and compact high‐loading electrodes using traditional slurry processing. Using this approach, electrodes with up to 14.9 mg cm −2 sulfur loading and an extremely low electrolyte/sulfur ratio as low as 3.5: 1 µL mg −1 are obtained. This study sheds light on the essential role of multifaceted cathode design and further on the challenges facing lithium metal anodes in building high volumetric energy density lithium–sulfur batteries. Abstract : A multifunctional and hierarchically structured sulfur composite is coupled with an in situ cross‐linked binder to construct stable and high volumetric energy density lithium–sulfur batteries. A hybrid sulfur host by alternately stacking graphene and layered carbon nitride embraces high conductivity and polysulfide adsorptivity. The elastomeric binder enables compact, high‐loading electrodes. Cells with up to 14.9 mg cm −2 sulfur loading and an electrolyte/sulfur ratio as low as 3.5:1 µL mg −1 are obtained.