Bringing Conducting Polymers to High Order: Toward Conductivities beyond 105 S cm−1 and Thermoelectric Power Factors of 2 mW m−1 K−2. Issue 24 (9th May 2019)

• Record Type: Journal Article
• Authors: Vijayakumar, Vishnu; Zhong, Yuhan; Untilova, Viktoriia; Bahri, Mounib; Herrmann, Laurent; Biniek, Laure; Leclerc, Nicolas; Brinkmann, Martin
• Is Part Of: Advanced energy materials. Volume 9:Issue 24(2019)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2019-05-09
• Subjects: conducting polymers -- organic thermoelectrics -- polymer crystallization -- thin films; Energy harvesting -- Materials -- Periodicals; Energy conversion -- Materials -- Periodicals; Energy storage -- Materials -- Periodicals; Photovoltaics -- Periodicals; Fuel cells -- Periodicals; Thermoelectric materials -- Periodicals; 621.31
• DOI: 10.1002/aenm.201900266
• Languages: English
• ISSNs: 1614-6832

Abstract

Abstract: Here, an effective design strategy of polymer thermoelectric materials based on structural control in doped polymer semiconductors is presented. The strategy is illustrated for two archetypical polythiophenes, e.g., poly(2, 5‐bis(3‐dodecyl‐2‐thienyl)thieno[3, 2‐ b ]thiophene) (C12 ‐PBTTT) and regioregular poly(3‐hexylthiophene) (P3HT). FeCl3 doping of aligned films results in charge conductivities up to 2 × 10 5 S cm −1 and metallic‐like thermopowers similar to iodine‐doped polyacetylene. The films are almost optically transparent and show strongly polarized near‐infrared polaronic bands (dichroic ratio >10). The comparative study of structure–property correlations in P3HT and C12 ‐PBTTT identifies three conditions to obtain conductivities beyond 10 5 S cm −1 : i) achieve high in‐plane orientation of conjugated polymers with high persistence length; ii) ensure uniform chain oxidation of the polymer backbones by regular intercalation of dopant molecules in the polymer structure without disrupting alignment of π‐stacked layers; and iii) maintain a percolating nanomorphology along the chain direction. The highly anisotropic conducting polymer films are ideal model systems to investigate the correlations between thermopower S and charge conductivity σ. A scaling law S ∝ σ −1/4 prevails along the chain direction, but a different S ∝ −ln(σ) relation is observed perpendicular to the chains, suggesting different charge transport mechanisms. The simultaneous increase of charge conductivity and thermopower along the chain direction results in a substantial improvement of thermoelectric power factors up to 2 mW m −1 K −2 in C12 ‐PBTTT. Abstract : An effective design strategy of polymer thermoelectric materials based on structural control in doped polymer semiconductors leads to a substantial improvement of charge conductivity (>10 5 S cm −1 ) and thermoelectric power factors (2 mW m −1 K −2 ). The highly anisotropic conducting polymer films are ideal model systems to investigate the correlations between thermopower S and charge conductivity σ.