Cover Feature: Unravelling the Enhanced High‐Temperature Performance of Lithium‐Rich Oxide Cathode with Methyl Diphenylphosphinite as Electrolyte Additive (ChemElectroChem 12/2018). Issue 12 (30th May 2018)

• Record Type: Journal Article
• Authors: Lou, Shuaifeng; Ma, Yulin; Zhou, Zhenxin; Huo, Hua; Zuo, Pengjian; Cheng, Xinqun; Qu, Xiaohui; Gao, Yunzhi; Du, Chunyu; Yin, Geping
• Is Part Of: ChemElectroChem. Volume 5:Issue 12(2018)
• Page Start: 1535
• Page End: 1535
• Publication Date: 2018-05-30
• Subjects: cathode -- electrolyte additive -- lithium-ion batteries -- manganese-rich oxide -- methyl diphenylphosphinite; Electrochemistry -- Periodicals; 541.37
• DOI: 10.1002/celc.201800609
• Languages: English
• ISSNs: 2196-0216

Abstract

Abstract : The Cover Feature illustrates the protection effects of the cathodes interfacial layer after adding the methyl diphenylphosphinite (MDP) additive into the electrolyte. MDP participates in the interfacial reaction of cathodes through the peroxidation behavior, and forms a robust protective film with interaction between the P−O species and transition‐metal elements. The film prevents the cathodes being attacked by HF in the electrolyte, leading to an enhanced high‐temperature performance of lithium‐rich oxide cathodes. More information can be found in the Article by Y. Ma and co‐workers on page 1569 in Issue 12, 2018 (DOI: 10.1002/celc.201800061 ).