On‐Surface Assembly of Au‐Dicyanoanthracene Coordination Structures on Au(111). Issue 18 (28th May 2019)

• Record Type: Journal Article
• Authors: Yan, Linghao; Pohjavirta, Ilona; Alldritt, Benjamin; Liljeroth, Peter
• Is Part Of: Chemphyschem. Volume 20:Issue 18(2019)
• Page Start: 2297
• Page End: 2300
• Publication Date: 2019-05-28
• Subjects: metal-organic coordination -- On‐Surface Synthesis -- scanning tunneling microscopy and spectroscopy -- supramolecular self-assembly -- ultrahigh vacuum; Chemistry, Physical and theoretical -- Periodicals; 541.05
• DOI: 10.1002/cphc.201900255
• Languages: English
• ISSNs: 1439-4235

Abstract

Abstract: On‐surface metal‐organic coordination provides a promising way for synthesizing different two‐dimensional lattice structures that have been predicted to possess exotic electronic properties. Using scanning tunneling microscopy (STM) and spectroscopy (STS), we studied the supramolecular self‐assembly of 9, 10‐dicyanoanthracene (DCA) molecules on the Au(111) surface. Close‐packed islands of DCA molecules and Au‐DCA metal‐organic coordination structures coexist on the Au(111) surface. Ordered DCA3 Au2 metal‐organic networks have a structure combining a honeycomb lattice of Au atoms with a kagome lattice of DCA molecules. Low‐temperature STS experiments demonstrate the presence of a delocalized electronic state containing contributions from both the gold atom states and the lowest unoccupied molecular orbital of the DCA molecules. These findings are important for the future search of topological phases in metal‐organic networks combining honeycomb and kagome lattices with strong spin‐orbit coupling in heavy metal atoms. Abstract : On‐surface self‐assembly of 9, 10‐dicyanoanthracene (DCA) molecules on the Au(111) surface is studied to target honeycomb/kagome networks containing heavy‐metal atoms with strong spin‐orbit interaction. Coexisting close‐packed islands of DCA molecules and Au‐DCA coordination structures are found. Ordered DCA3 Au2 metal‐organic networks exhibit a delocalized electronic state spread over both the gold atoms and the DCA molecules.