Impact of Eu3+ ion substitution on structural, magnetic and microwave traits of Ni–Cu–Zn spinel ferrites. Issue 8 (1st June 2020)

• Record Type: Journal Article
• Authors: Almessiere, M.A.; Slimani, Y.; Güngüneş, H.; Kostishyn, V.G.; Trukhanov, S.V.; Trukhanov, A.V.; Baykal, A.
• Is Part Of: Ceramics international. Volume 46:Issue 8(2020)Part A
• Page Start: 11124
• Page End: 11131
• Publication Date: 2020-06-01
• Subjects: Spinel ferrites -- Nanoparticles -- Mossbauer spectra -- Magnetic structure -- Microwave parameters; Ceramics -- Periodicals; Céramique industrielle -- Périodiques; Ceramics; Periodicals; Electronic journals; 666
• DOI: 10.1016/j.ceramint.2020.01.132
• Languages: English
• ISSNs: 0272-8842

Abstract

Abstract: Partially europium (Eu) substituted Ni0.4 Cu0.2 Zn0.4 Eux Fe2-x O4 (0.0 ≤ x ≤ 0.10) nanostructured spinel ferrites (NSFs) were produced by sol-gel auto-combustion strategy. The XRD analyses verified the existence of the single-phase composition in all the investigated samples. The Mössbauer spectra were used to estimate the values of the line-width disparity, isomeric shift (IS), quadrupole splitting, and hyperfine magnetic field (HMF). The values of HMF of the A and B sites decreased with the rise in Eu substitutions. The paramagnetic contribution of the NSFs increased with the rise in Eu 3+ contents. The S-parameters of the proposed NSFs were measured using co-axial method. The frequency dispersions of the permittivity and permeability were utilized to determine the reflection losses in the 1–20 GHz frequency range. The occurrences of the natural ferromagnetic resonance (NFMR) enabled substantial absorption of the electromagnetic energy ranged from 2.5 to 9.5 GHz. There was established a strong correlation between the level of chemical substitution (x) and amplitude-frequency characteristics of the studied spinel ferrites was established. Furthermore, the increase of Eu substitution strongly influenced the frequency characteristics of the NSFs. Anomalous changing of the resonant amplitude (more than 4 times) was shown. This can be explained by the appearance of indirect exchange interactions between Fe 3+ (3 d 5 ) and Eu 3+ (4f 6 ) electronic shells. Results revealed a potential for practical applications of such kinds of materials in functional radio electronic devices.