Magnetic N‐Enriched Fe3C/Graphitic Carbon instead of Pt as an Electrocatalyst for the Oxygen Reduction Reaction. Issue 14 (2nd March 2016)

• Record Type: Journal Article
• Authors: Wang, Xiaobai; Zhang, Peng; Wang, Wei; Lei, Xiang; Yang, Hua
• Is Part Of: Chemistry. Volume 22:Issue 14(2016)
• Page Start: 4863
• Page End: 4869
• Publication Date: 2016-03-02
• Subjects: fuel cells -- magnetic properties -- nanomaterials -- nitrogen -- reduction; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201505138
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract: A series of Fe3 C/C‐N x nanoparticles (NPs) with different nitrogen content are prepared by a simple one‐pot route. In the synthetic procedure, aniline and acetonitrile are simultaneously used as the carbon and nitrogen source. The effect of calcination temperature on the structural and functional properties of the materials is investigated. Magnetic measurement shows that the sample prepared at 800 °C (Fe3 C/C‐N800 NPs) possesses the highest Ms value of 77.2 emu g −1 . On testing as oxygen reduction reaction (ORR) catalysts, the sample prepared at 750 °C (Fe3 C/C‐N750 NPs) shows the best ORR performance among the series, with a more positive onset potential (+0.99 V vs. RHE), higher selectivity (number of electron transfer n≈3.93), longer durability, and stronger tolerance against methanol crossover than commercial Pt/C catalysts in a 0.1 m KOH solution. Moreover, in acidic solution, the excellent ORR activity and stability are also exhibited. Abstract : Magnetic nanomaterials : A series of Fe3 C/C‐N x nanoparticles (NPs) with different nitrogen content are prepared by a simple one‐pot route (see figure). The materials exhibit excellent magnetic properties and oxygen reduction reaction (ORR) activities.