Absorption and Oxidation of Nitrogen Oxide in Ionic Liquids. Issue 33 (7th July 2016)

• Record Type: Journal Article
• Authors: Kunov‐Kruse, Andreas J.; Thomassen, Peter L.; Riisager, Anders; Mossin, Susanne; Fehrmann, Rasmus
• Is Part Of: Chemistry. Volume 22:Issue 33(2016)
• Page Start: 11745
• Page End: 11755
• Publication Date: 2016-07-07
• Subjects: gas absorption -- ionic liquids -- IR spectroscopy -- nitric acid -- NOx; Chemistry -- Periodicals; 540
• DOI: 10.1002/chem.201601166
• Languages: English
• ISSNs: 0947-6539

Abstract

Abstract: A new strategy for capturing nitrogen oxide, NO, from the gas phase is presented. Dilute NO gas is removed from the gas phase by ionic liquids under ambient conditions. The nitrate anion of the ionic liquid catalyzes the oxidation of NO to nitric acid by atmospheric oxygen in the presence of water. The nitric acid is absorbed in the ionic liquid up to approximately one mole HNO3 per mole of the ionic liquid due to the formation of hydrogen bonds. The nitric acid can be desorbed by heating, thereby regenerating the ionic liquid with excellent reproducibility. Here, time‐resolved in‐situ spectroscopic investigations of the reaction and products are presented. The procedure reveals a new vision for removing the pollutant NO by absorption into a non‐volatile liquid and converting it into a useful bulk chemical, that is, HNO3 . Abstract : The answer is NO ! A new vision for removing NO from exhaust gases is presented. Nitrate‐based ionic liquids catalyze the fast oxidation of NO by O2 to nitric acid (see figure), which is accumulated in the non‐volatile ionic liquid in a ratio of 1:1 at room temperature. The reaction is followed in situ in a thin film by ATR‐FTIR spectroscopy. A mechanism for the catalytic reaction is suggested.