In-situ growth of high-density ultrafine Ag3PO4 nanoparticles on 3D TiO2 hierarchical spheres for enhanced photocatalytic degradation of organic pollutants. (14th September 2020)

• Record Type: Journal Article
• Authors: Qian, Degui; Fang, Desheng; Xu, Yifeng; Hu, Haihua; Lin, Ping; Ding, Zixuan; Wang, Peng; Xu, Lingbo; Cui, Can
• Is Part Of: Nanotechnology. Volume 31:Number 48(2020)
• Publication Date: 2020-09-14
• Subjects: Ag3PO4 nanoparticles -- TiO2 hierarchical spheres -- photocatalyst -- MB degradation; Nanotechnology -- Periodicals; Nanotechnology -- Periodicals; Nanotechnology; Publications périodiques; Nanotechnologies; Periodicals; 620.5
• DOI: 10.1088/1361-6528/abb0b9
• Languages: English
• ISSNs: 0957-4484

Abstract

Abstract: Silver phosphate (Ag3 PO4, APO) has attracted intense attention as a visible-light-driven photocatalyst, but its large-scale application is limited by severe charge recombination and inevitable photo-corrosion. Various rational APO-based heterostructures composed of APO nanoparticles (NPs) and band-matched semiconductor support are designed to address the above issues. Nevertheless, the size, density, stability, and dispersion of APO NPs are critical challenges for the photocatalytic performance of APO-based photocatalysts. Here, three-dimensional (3D) self-assembled TiO2 hierarchical spheres (THS) prepared by a simple one-step hydrothermal method are employed as innovative support, and ultrafine high-density APO NPs with an average size of about 3 nm are successfully deposited and uniformly dispersed throughout THS to form hierarchical THS/APO composites. The novel THS/APO microstructure provides abundant reactive sites for photocatalytic reactions and promotes the photogenerated charge separation and transfer due to the ultrafine size of APO NPs and the TiO2 /APO Type-II heterojunction. As a result, the THS/APO composites show significant improvement in photocatalytic activity and stability in methylene blue (MB) degradation. The reaction constant of THS/APO composites far exceeds that of either THS or APO, roughly 16 and 7 times higher than that of THS and APO under full-spectrum light, and 41 and 4 times higher under visible light. Our results strongly suggest new insights into the low-cost, large-scale application of high-efficiency APO-based photocatalyst.