ZIF-67 derived carbon wrapped discontinuous CoxP nanotube as anode material in high-performance Li-ion battery. (September 2020) - Liu, Y.
Abstract: Transition metal phosphides (TMPs) are prospective anode materials for lithium-ion batteries (LIBs) due to their high theoretical capacities and low redox voltages. Herein, we report a template directing method to develop a tube-sheath hybrid composing of cobalt phosphide particles encapsulated in metal organic frameworks (MOFs) derived N-doped carbon sheaths (Cox P@NC). The utilization of directing template leads to a homogenous distribution of the subsequently formed cobalt phosphide particles, restrains the aggregation of cobalt phosphides, and thus results in the superb rate capability and cyclability. Contributable to the integrated merits of the interior downsized cobalt phosphide particles and the outer ZIF-67 derived porous carbon sheath, the volume expansion during cycling is effectively suppressed. The Cox P@NC hybrid shows superb electrochemical performance as anode material for LIB, with good reversible capacity of 928 mAh·g −1 after 100 cycles at 0.1 A g −1, and high stability of 526 mAh·g −1 after 600 cycles at 1.0 A g −1 . This work provides a route for rational design of MOF derived carbon-based anode material for LIB, which could also be applied as a promising platform in diverse field. Graphical abstract: A novel MOF-derived carbon-based composite (Cox P@NC) demonstrated superior lithium storage as an anode for lithium-ion batteries (LIBs). Image 1 Highlights: Cox P@NC hybrid with tube-sheath structure was developed as anode material for LIB. Template directing route results in discrete Cox P tube and ZIF-67 derived carbon sheath. Volume expansion of encapsulated Cox P is suppressed due to tube-sheath structure. Cox P based LIB shows performance with high reversibility and stability.