Removing hydrogen sulfide from a feed stream using suitable adsorbent materials. (1st November 2020)

• Record Type: Journal Article
• Authors: Ahn, Yongtae; Pandi, Kalimuthu; Lee, Miyeon; Choi, Jaeyoung
• Is Part Of: Journal of cleaner production. Volume 272(2020)
• Publication Date: 2020-11-01
• Subjects: Adsorption -- Biogas desulfurization -- H2S -- Bench-scale -- Breakthrough models; Factory and trade waste -- Management -- Periodicals; Manufactures -- Environmental aspects -- Periodicals; Déchets industriels -- Gestion -- Périodiques; Usines -- Aspect de l'environnement -- Périodiques; 628.5
• DOI: 10.1016/j.jclepro.2020.122849
• Languages: English
• ISSNs: 0959-6526

Abstract

Abstract: A series of materials, including sand (S) silica blue (SB), iron-exchanged sand (IES), zeolite 13X (Z), iron-exchanged zeolites (IEZ), and the waste material acid mine drainage sludge (AMDS), were used as adsorbents for the removal of hydrogen sulfide (H2 S) from a feed stream in a pilot (bench)-scale study. Artificially polluted H2 S gas streams were created using a gas cylinder with 10, 000 ppmv of H2 S in nitrogen (N2 ), which was used for further dilution. The adsorption performance of each sorbent material was assessed by dynamic breakthrough analysis. The sorbents were analyzed via Fourier transform infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), X-Ray fluorescence spectrometry (XRF), X-ray diffraction (XRD), and Brunauer-Emmett-Teller (BET) analysis. The efficiency of H2 S removal was observed and compared between adsorbents under various operating conditions, such as different contact times and initial concentrations. The AMDS was discovered to have highest adsorption efficiency for H2 S, of all adsorbents studied here. The Yoon-Nelson, Thomas and Adam-Bohart models were applied to study the effects of H2 S concentration and flow rate on adsorption of H2 S on AMDS, and the maximum adsorption capacity of 312.73 g g −1 was attained at 1000 ppmv and 0.5 L min −1 of H2 S concentration and flow rate, respectively. This study found that all tested adsorbent materials have appreciable H2 S adsorption capacity and AMDS in particular is an appropriate adsorbent for treatment of H2 S-contaminated steam. Moreover, AMDS is a waste material and is available in abundance; hence, AMDS could be a practical choice for the adsorption of H2 S from biogas. Graphical abstract: Image 1 Highlights: The low-cost and renewable adsorbents were used for desulfurization. H2 S dynamic adsorption were performed using column study. AMDS is an economical, eco-friendly, high in abundance and easy handling adsorbent. The outstanding adsorption efficiencies of AMDS confirm as practical adsorbent.