FeNiSx@MoS2 Heterostructure: A Bioinspired Nonprecious Electrocatalyst for the Hydrogen Evolution Reaction in Acidic and Basic Media. Issue 15 (10th August 2020)

• Record Type: Journal Article
• Authors: Bolar, Saikat; Shit, Subhasis; Murmu, Naresh Chandra; Kuila, Tapas
• Is Part Of: ChemElectroChem. Volume 7:Issue 15(2020)
• Page Start: 3324
• Page End: 3335
• Publication Date: 2020-08-10
• Subjects: biomimetic synthesis -- electrocatalysis -- hydrogen evolution reaction -- heterostructures -- Tafel slope; Electrochemistry -- Periodicals; 541.37
• DOI: 10.1002/celc.202000799
• Languages: English
• ISSNs: 2196-0216

Abstract

Abstract: FeNiS x @MoS2 (INSMS) heterostructure is designed and developed to achieve a structural and functional analogue with biological enzyme active sites that catalyze hydrogen production. A two‐step synthetic method is applied to develop the heterostructure. As‐prepared INSMS integrates FeNiSx (INS) nanosheets on the surface of the MoS2 nanopetals. The electrocatalyst demonstrates robust hydrogen evolution reaction (HER) activity due to the selective decoration of INS nanosheets over MoS2, owing to their different solubility product values. Two different phases of INS nanosheets are formed in INSNS due to the topotactic transition of INS nanosheets, as confirmed by the XRD and HR‐TEM analysis. In the HER, INSMS requires overpotentials of 110 and 155 mV at 10 mA cm −2 with Tafel slope values of 34 and 93 mV dec −1 in acidic and alkaline medium, respectively. This improved electrochemical performance is generated by the modification of the electron‐hole separation at the heterostructure interface and interlinked active edge sites at the interface. Abstract : Inspired by design : A bioinspired FeNiS x @MoS2 heterostructure is fabricated by using a solvothermal technique for efficient hydrogen evolution in acidic and alkaline pH media. The FeNiS x nanosheets formed over the MoS2 nanoflowers (different Ksp value) significantly enhance the catalytic performance through a synergistic effect. Overpotentials of 110 and 155 mV are required at a current density of 10 mA cm −2 in acidic and alkaline medium, respectively.