A Light‐Switchable Liquid Metamaterial Mirror. Issue 17 (11th June 2020)

• Record Type: Journal Article
• Authors: Cormier, Sean; Salmon, Andrew R.; Kos, Dean; Baumberg, Jeremy J.
• Is Part Of: Advanced optical materials. Volume 8:Issue 17(2020)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2020-06-11
• Subjects: gold nanoparticles -- metafilms -- metamaterials -- optical nonlinearity -- thermoresponsive; Optical materials -- Periodicals; Photonics -- Periodicals; 620.11295
• DOI: 10.1002/adom.202000396
• Languages: English
• ISSNs: 2195-1071

Abstract

Abstract: A metamaterial film composed of gold nanoparticles wrapped in thin thermoresponsive polymer shells is described. The nanoparticle shells are kept partially hydrated so that the film acts as a "liquid mirror" and shows subtle interactions due to its composite metamaterial nature. Optically heating the film collapses the polymer, increasing the gold fill fraction and raising the reflectivity. This in turn decreases the optothermal absorption, making both the reflectivity and optothermal absorption nonlinear. When the polymer collapses, the film buckles due to thermophoretic flows competing against surface tension. These interactions generate a remarkable array of dynamic behaviors. Exposing the films to light causes an insulator‐to‐metal transition. Defects can be healed by returning the film to the liquid phase. Laser illumination of micrometer‐scale regions generates local dimples at low power and sinters microscale tracks at high power. When microbeads are combined into these films, optical switching results in quenching of their photoluminescence as well as the ability to manipulate their spatial position in real time. Abstract : An active metamaterial film is described. This film is composed of a layer of gold nanoparticles wrapped in temperature‐responsive polymer shells. Optically heating the film collapses the polymer shells, increasing the gold fill fraction and dramatically altering the metaproperties. This leads to nonlinear optical responses as well as shape deformations that can manipulate embedded beads.