Cover Picture: An Ultrastable, Small {Ag7}5+ Nanocluster within a Triangular Hollow Polyoxometalate Framework (Angew. Chem. Int. Ed. 38/2020). Issue 38 (4th August 2020)

• Record Type: Journal Article
• Authors: Yonesato, Kentaro; Ito, Hiroyasu; Yokogawa, Daisuke; Yamaguchi, Kazuya; Suzuki, Kosuke
• Is Part Of: Angewandte Chemie international edition. Volume 59:Issue 38(2020)
• Page Start: 16249
• Page End: 16249
• Publication Date: 2020-08-04
• Subjects: cluster compounds -- polyoxometalates -- silver nanoclusters -- template synthesis; Chemistry -- Periodicals; 540
• DOI: 10.1002/anie.202009974
• Languages: English
• ISSNs: 1433-7851

Abstract

Abstract : An ultrastable silver nanocluster was synthesized by K. Yamaguchi, K. Suzuki et al. in their Communication on page 16361 by using lacunary polyoxometalates. In the cover picture, the green polyhedra represent lacunary polyoxometalates and the light gray spheres silver atoms. While small silver nanoclusters are typically highly fragile, the small Ag7 nanocluster shows unprecedented stability when surrounded by a triangular hollow polyoxometalate framework.