Preliminary study on FeGd alloys as binary alloys and master alloys for potential spent nuclear fuel (SNF) application. (September 2020)

• Record Type: Journal Article
• Authors: Lee, Sang-Wook; Ahn, Ji-Ho; Moon, Byung-Moon; Kim, DongEung; Oh, SeKwon; Kim, Young-Jig; Jung, Hyun-Do
• Is Part Of: Materials & design. Volume 194(2020)
• Publication Date: 2020-09
• Subjects: Gadolinium -- Iron -- Stainless steel -- Neutron absorbing material -- Thermal conductivity -- Corrosion resistance; Materials -- Periodicals; Engineering design -- Periodicals; Matériaux -- Périodiques; Conception technique -- Périodiques; Electronic journals; 620.11
• DOI: 10.1016/j.matdes.2020.108906
• Languages: English
• ISSNs: 0264-1275

Abstract

Abstract: One of the biggest challenges of nuclear industries is to fabricate safe, stable and efficient materials for the storage and transportation of spent nuclear fuels (SNFs), these materials are known as neutron shielding and absorbing materials. Recently, Gd has received much attention as a neutron absorbing material in SNF applications owing to its high neutron absorption capability. Herein, we propose novel FeGd alloys as binary alloys and master alloys for potential materials in nuclear applications. FeGd alloys with 20, 55 and 80 wt% Gd were selected based on the FeGd phase diagram. All fabricated FeGd alloys had higher hardnesses than pure Fe due to the formed FeGd phases, and the Fe-rich phase had a higher hardness than the Gd-rich phase. On the other hand, corrosion resistance of the FeGd alloys decreased as the Gd content increased. Satisfactory Gd-based intermetallic dispersion and modifying effects were obtained by casting Fe and stainless-steel alloy with Fe80Gd. The average intermetallic size in the stainless-steel alloy remarkably decreased with a decrease in the average distance between Gd-based intermetallics. FeGd alloys possess requisite hardness, thermal conductivity, and corrosion resistance as well as dispersion ability of intermetallics; hence, they show potential as promising candidates for SNF applications. Graphical abstract: Unlabelled Image Highlights: FeGd alloys were fabricated for potential materials in nuclear applications. FeGd alloys containing 20, 55 and 80 wt% Gd were fabricated by a VAM process. FeGd possess requisite hardness, thermal conductivity, and corrosion resistance. A uniform microstructure of Gd containing alloy was obtained using Fe80Gd alloy.