Lignin-based magnetic activated carbon for p-arsanilic acid removal: Applications and absorption mechanisms. (November 2020)

• Record Type: Journal Article
• Authors: Wu, Qiong; Ye, Xiaoxia; Lv, Yuancai; Pei, Ruihan; Wu, Minya; Liu, Minghua
• Is Part Of: Chemosphere. Volume 258(2020)
• Publication Date: 2020-11
• Subjects: p-arsanilic acid -- Lignin -- Magnetic -- Activated carbon -- Adsorption mechanisms; Pollution -- Periodicals; Pollution -- Physiological effect -- Periodicals; Environmental sciences -- Periodicals; Atmospheric chemistry -- Periodicals; 551.511
• DOI: 10.1016/j.chemosphere.2020.127276
• Languages: English
• ISSNs: 0045-6535

Abstract

Abstract: It is crucial for water environment security to remove its p -arsanilic acid ( p -ASA) efficiently. Namely, removing p -arsanilic acid from aqueous media through magnetic separation, has become a novel method of removing toxic pollutants from water. Batch adsorption experiments demonstrated a higher adsorption of lignin-based magnetic activated carbon (201.64 mg g −1 ) toward p -ASA. In addition, LMAC nanoparticles exhibited typical magnetism (35.63 emu g −1 of saturation magnetization) and could be easily separated from the aqueous solution. Meanwhile, the endothermic adsorption of p -ASA over LMAC could spontaneously proceed and be well described by the pseudo-first-order and pseudo-second-order model as well as the intra-particle diffusion model. Moreover, the mechanisms during p -ASA adsorption over LMAC included the electrostatic attraction, surface complexation, π-π stacking and hydrogen bonding interaction. Importantly, lignin-based magnetic activated carbon has high absorbability and preferable reusability in real water samples. Consequently, this paper provides insights into preparation of the lignin-based magnetic activated carbon may be potential adsorbents for the remediation of organoarsenic compounds. Graphical abstract: Image 1 Highlights: The novel adsorbent LMAC was synthesized and employed for the adsorption of p -arsanilic acid. The p -arsanilic acid onto LMAC is more significant at lower pH. Plausible adsorption mechanism and coordination were further discussed.