A fast and simple B–C bond formation in metallacarboranes avoiding halometallacarboranes and transition metal catalysts. Issue 11 (28th February 2020)

• Record Type: Journal Article
• Authors: Buades, Ana B.; Kelemen, Zsolt; Arderiu, Víctor S.; Zaulet, Adnana; Viñas, Clara; Teixidor, Francesc
• Is Part Of: Dalton transactions. Volume 49:Issue 11(2020)
• Page Start: 3525
• Page End: 3531
• Publication Date: 2020-02-28
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c9dt04695j
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : An electrophilic substitution on metallacarboranes by using a stabilized carbocation that can be made in situ is reported for the first time. Abstract : An electrophilic substitution on metallacarboranes by using a stabilized carbocation that can be made in situ is reported for the first time. This new synthetic methodology provides a new perspective on easy metallacarborane derivatization with organic fragments, which enhances the properties of both fragments and widens their possible applications.