CO2 capture with room temperature ionic liquids; coupled absorption/desorption and single module absorption in membrane contactor. (21st September 2020)

• Record Type: Journal Article
• Authors: Sohaib, Qazi; Vadillo, Jose Manuel; Gómez-Coma, Lucía; Albo, Jonathan; Druon-Bocquet, Stéphanie; Irabien, Angel; Sanchez-Marcano, José
• Is Part Of: Chemical engineering science. Volume 223(2020)
• Publication Date: 2020-09-21
• Subjects: Coupled absorption/desorption -- Pseudo steady state modelling -- Carbon capture -- Membrane contactors -- Imidazolium ionic liquids; Chemical engineering -- Periodicals; Génie chimique -- Périodiques; Chemical engineering; Periodicals; Electronic journals; 660
• DOI: 10.1016/j.ces.2020.115719
• Languages: English
• ISSNs: 0009-2509

Abstract

Graphical abstract: Highlights: Coupled Absorption/Desorption and Single Module Absorption setups were developed for CO2 capture. Imidazolium based room temperature ionic liquids were coupled with membrane absorber and stripper. A pseudo-steady state modelling approach was also implemented for sensitivity and parametric analysis. Coupled Absorption/Desorption arrangement was able to keep long term high absorption performance. Long term zero CO2 concentration at stripper outlet was simulated by optimizing the operating parameters. Abstract: A membrane gas CO2 capture setup, based on the concept of single module absorption and single cycle coupled absorption/desorption, was developed in this work. Ionic liquids (ILs) 1-ethyl-3-methylimidazolium methylsulfate ([emim][MS]) and 1-ethyl-3-methylimidazolium dicyanamide ([emim][DCA]) were used as absorbents. The CO2 absorption rate decreased initially and reached to a nearly constant value achieving pseudo steady state. Coupled absorption/desorption revealed very high performance by retaining 82% and 66% absorption efficiency, for [emim][MS] and [emim][DCA], respectively, even after 70 min of operation. Mass transfer coefficients of the coupled absorption/desorption at pseudo steady state were 9 and 5 folds higher than single module absorption, for [emim][MS] and [emim][DCA], respectively. Parametric analysis for the membrane absorber outlet concentration and optimization of the parameters to achieve zero concentration at the membrane stripper outlet were studied in simulations. As a conclusion, coupled absorption/desorption in combination with ILs, can be considered very suitable for continuous post-combustion carbon capture.