Catalyst Design for Electrochemical Oxygen Reduction toward Hydrogen Peroxide. (18th June 2020) - Jiang, Kun
Abstract: Precise electrochemical synthesis under ambient conditions has provided emerging opportunities for renewable energy utilization. Among many promising systems, the production of hydrogen peroxide (H2 O2 ) from the cathodic oxygen reduction reaction (ORR) has attracted considerable interest in past decades due to the increasing market demands and the vital role of ORR in the electrocatalysis field. This work describes recent advances in cathodic materials for H2 O2 synthesis from 2e - ORR. By using Pt as a stereotype, the tuning knobs are overviewed, including the intrinsic binding strength of oxygenated species, the intermediate diffusion path and the isolation of Pt–Pt ensembles that enable 2e - ORR pathway from 4e - total reduction. This knowledge is successfully applied to other transition metal systems and leads to the discovery of more efficient alloy catalysts with balanced improvement on both activity and selectivity. In addition, mesostructure engineering and heteroatoms doping strategies on carbon‐based materials, which significantly boost the H2 O2 production efficiency as compared to intact carbon sites, are also reviewed. Finally, future directions and challenges of transferring developed catalysts from lab scale tests to pilot plant operations are briefly outlooked. Abstract : Electrocatalytic oxygen reduction into hydrogen peroxide, powered by renewable energy sources with green inputs of air and water, is a promising route for decentralized H2 O2 generation and its onsite application. A focus review of designing principles and recent progress on cathodic materials for enhanced O2 reduction to H2 O2 is provided.