Synthesis and hetero-Diels–Alder reactions of enantiomerically pure dihydro-1H-azepines. Issue 68 (24th July 2020)
- Record Type:
- Journal Article
- Title:
- Synthesis and hetero-Diels–Alder reactions of enantiomerically pure dihydro-1H-azepines. Issue 68 (24th July 2020)
- Main Title:
- Synthesis and hetero-Diels–Alder reactions of enantiomerically pure dihydro-1H-azepines
- Authors:
- Craig, Donald
Spreadbury, Samuel R. J.
White, Andrew J. P. - Abstract:
- Abstract : Thermolysis of enantiomerically pure 3-substituted 7, 7-dihalo-2-azabicyclo[4.1.0]heptanes in the presence of K2 CO3 gives in good yields 2-alkyl-6-halo-1-tosyl-2, 3-dihydro-1 H -azepines. Abstract : Thermolysis of enantiomerically pure 3-substituted 7, 7-dihalo-2-azabicyclo[4.1.0]heptanes in the presence of K2 CO3 gives in good yields 2-alkyl-6-halo-1-tosyl-2, 3-dihydro-1 H -azepines. These undergo highly stereoselective [4+2] cycloaddition reactions with heterodienophiles and arylation/alkenylation under Suzuki conditions.
- Is Part Of:
- Chemical communications. Volume 56:Issue 68(2020)
- Journal:
- Chemical communications
- Issue:
- Volume 56:Issue 68(2020)
- Issue Display:
- Volume 56, Issue 68 (2020)
- Year:
- 2020
- Volume:
- 56
- Issue:
- 68
- Issue Sort Value:
- 2020-0056-0068-0000
- Page Start:
- 9803
- Page End:
- 9806
- Publication Date:
- 2020-07-24
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d0cc04413j ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 13886.xml