Exploring cycling induced crystallographic change in NMC with X-ray diffraction computed tomography. Issue 32 (25th June 2020)

• Record Type: Journal Article
• Authors: Daemi, Sohrab R.; Tan, Chun; Vamvakeros, Antonis; Heenan, Thomas M. M.; Finegan, Donal P.; Di Michiel, Marco; Beale, Andrew M.; Cookson, James; Petrucco, Enrico; Weaving, Julia S.; Jacques, Simon; Jervis, Rhodri; Brett, Dan J. L.; Shearing, Paul R.
• Is Part Of: Physical chemistry chemical physics. Volume 22:Issue 32(2020)
• Page Start: 17814
• Page End: 17823
• Publication Date: 2020-06-25
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/d0cp01851a
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : This study presents the application of XRD-CT combined with FIB-SEM to analyze the crystal dimensions of LiNi0.33 Mn0.33 Co0.33 O2 electrodes and spatially localise the change in unit cell dimensions as a result of electrochemical cycling. Abstract : This study presents the application of X-ray diffraction computed tomography for the first time to analyze the crystal dimensions of LiNi0.33 Mn0.33 Co0.33 O2 electrodes cycled to 4.2 and 4.7 V in full cells with graphite as negative electrodes at 1 μm spatial resolution to determine the change in unit cell dimensions as a result of electrochemical cycling. The nature of the technique permits the spatial localization of the diffraction information in 3D and mapping of heterogeneities from the electrode to the particle level. An overall decrease of 0.4% and 0.6% was observed for the unit cell volume after 100 cycles for the electrodes cycled to 4.2 and 4.7 V. Additionally, focused ion beam-scanning electron microscope cross-sections indicate extensive particle cracking as a function of upper cut-off voltage, further confirming that severe cycling stresses exacerbate degradation. Finally, the technique facilitates the detection of parts of the electrode that have inhomogeneous lattice parameters that deviate from the bulk of the sample, further highlighting the effectiveness of the technique as a diagnostic tool, bridging the gap between crystal structure and electrochemical performance.