D-(+)-Glucose-triggered metallogel to metallogel transition. Issue 32 (6th August 2020)

• Record Type: Journal Article
• Authors: Mahendar, Chinthakuntla; Dixit, Manish Kumar; Kumar, Yeeshu; Dubey, Mrigendra
• Is Part Of: Journal of materials chemistry. Volume 8:Issue 32(2020)
• Page Start: 11008
• Page End: 11012
• Publication Date: 2020-08-06
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d0tc02877k
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : The metallogel to metallogel transition triggered in response to a chemical reaction with d -(+)-glucose has been demonstrated. The conformational changes in the gelator p -H6 BAL and conductance properties during the transition were well studied. Abstract : A chiral metallogel (2% w/v, DMSO) has been obtained from a phenylboronic acid-tagged l -tartaric-based symmetrical ligand ( p -H6 BAL ) and LiOH. The metallogel to metallogel transition triggered in response to a chemical reaction with d -(+)-glucose has been fully characterized using UV-vis, circular dichroism, FESEM, 1 H NMR, ESI-Mass, rheology and impedance spectroscopies.