Chemical looping beyond combustion – a perspective. Issue 3 (30th January 2020)

• Record Type: Journal Article
• Authors: Zhu, Xing; Imtiaz, Qasim; Donat, Felix; Müller, Christoph R.; Li, Fanxing
• Is Part Of: Energy & environmental science. Volume 13:Issue 3(2020)
• Page Start: 772
• Page End: 804
• Publication Date: 2020-01-30
• Subjects: Energy conversion -- Periodicals; Fuel switching -- Periodicals; Environmental sciences -- Periodicals; Environmental chemistry -- Periodicals; 333.79
• DOI: 10.1039/c9ee03793d
• Languages: English
• ISSNs: 1754-5692

Abstract

Abstract : Facilitated by redox catalysts capable of catalytic reactions and reactive separation, chemical looping offers exciting opportunities for intensified chemical production. Abstract : As a promising approach for carbon dioxide capture, chemical looping combustion has been extensively investigated for more than two decades. However, the chemical looping strategy can be and has been extended well beyond carbon capture. In fact, significant impacts on emission reduction, energy conservation, and value-creation can be anticipated from chemical looping beyond combustion (CLBC). This article aims to demonstrate the versatility and transformational benefits of CLBC. Specifically, we focus on the use of oxygen carriers or redox catalysts for chemical production – a $4 trillion industry that consumes 40.9 quadrillion BTU of energy. Compared to state-of-the-art chemical production technologies, we illustrate that chemical looping offers significant opportunities for process intensification and exergy loss minimization. In many cases, an order of magnitude reduction in energy consumption and CO2 emission can be realized without the needs for carbon dioxide capture. In addition to providing various CLBC examples, this article elaborates on generalized design principles for CLBC, potential benefits and pitfalls, as well as redox catalyst selection, design, optimization, and redox reaction mechanism.