Modification of the Near‐Infrared Spontaneous Emission in Er3+‐Activated Inverse Silica Opals. Issue 8 (29th November 2019)

• Record Type: Journal Article
• Authors: Chiappini, Andrea; Armellini, Cristina; Bazzanella, Nicola; Nodehi, Somayeh; Lukowiak, Anna; Pietralunga, Silvia Maria; Piccolo, Valentina; Zonta, Daniele; Nunzi Conti, Gualtiero; Righini, Giancarlo C.; Ferrari, Maurizio
• Is Part Of: Physica status solidi. Volume 257:Issue 8(2020)
• Page Start: n/a
• Page End: n/a
• Publication Date: 2019-11-29
• Subjects: concentration quenching -- inverse opals -- photoluminescence -- virtual cavity model; Solid state physics -- Periodicals; Solids -- Periodicals; Atomic structure -- Periodicals; 530.41
• DOI: 10.1002/pssb.201900476
• Languages: English
• ISSNs: 0370-1972

Abstract

Abstract : Ordered SiO2 :Er 3+ inverse opal films are fabricated by sol–gel technique in combination with a self‐assembly method to examine their potential as a suitable platform to tailor the spontaneous emission lifetime of Er 3+ ions and its concentration quenching (CQ). Good ordering on long‐range scale is evidenced by means of scanning electron microscopy, whereas reflectance measurements display a green bright color, as it results from optical Bragg diffraction from the (111) crystal planes. Moreover, it is observed that the spontaneous decay rates (SDRs) of the inverse opals are suppressed, in contrast to the corresponding reference samples, due to the modulation of the effective refractive index ( n eff ), in agreement with the virtual cavity model. At the same time, the reduced CQ of Er 3+ is attributed to the periodic empty cavity of the inverse opals. These results demonstrate that inverse opals can provide a tool for the enhancement of near‐infrared (NIR) luminescence. Abstract : The article reports on the realization of ordered SiO2 :Er 3+ inverse opal films obtained by sol–gel technique in combination with a self‐assembly method. This structure can be considered as a suitable tool for the enhancement of near‐infrared (NIR) luminescence; in fact, it demonstrates that it is possible to tailor the spontaneous emission lifetime of Er 3+ ions and concentration quenching.