Palladium/copper-cocatalyzed decarbonylative alkynylation of acyl fluorides with alkynylsilanes: synthesis of unsymmetrical diarylethynes. Issue 57 (15th June 2020)
- Record Type:
- Journal Article
- Title:
- Palladium/copper-cocatalyzed decarbonylative alkynylation of acyl fluorides with alkynylsilanes: synthesis of unsymmetrical diarylethynes. Issue 57 (15th June 2020)
- Main Title:
- Palladium/copper-cocatalyzed decarbonylative alkynylation of acyl fluorides with alkynylsilanes: synthesis of unsymmetrical diarylethynes
- Authors:
- Chen, Qiang
Fu, Liyan
Nishihara, Yasushi - Abstract:
- Abstract : Alkynylation of acyl fluorides with alkynylsilanes via palladium/copper-cocatalysed carbon–fluorine bond cleavage and sequential decarbonylation, which provide an efficient route to various unsymmetrical diarylethynes, have been disclosed. Abstract : Palladium/copper-cocatalyzed decarbonylative alkynylation of acyl fluorides with alkynylsilanes is described. This reaction not only effectively inhibits the formation of undesired homocoupled products by avoiding the addition of a base, but also exhibits a wide substrate scope to provide a general access to diverse unsymmetrical diarylethynes.
- Is Part Of:
- Chemical communications. Volume 56:Issue 57(2020)
- Journal:
- Chemical communications
- Issue:
- Volume 56:Issue 57(2020)
- Issue Display:
- Volume 56, Issue 57 (2020)
- Year:
- 2020
- Volume:
- 56
- Issue:
- 57
- Issue Sort Value:
- 2020-0056-0057-0000
- Page Start:
- 7977
- Page End:
- 7980
- Publication Date:
- 2020-06-15
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d0cc03309j ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 13890.xml