Optimized synthesis of fluorinated dithienyl-diketopyrrolopyrroles and new copolymers obtained via direct heteroarylation polymerization. (1st June 2020)

• Record Type: Journal Article
• Authors: Mamone, Marius; Bura, Thomas; Brassard, Samuel; Soligo, Eliane; He, Keqiang; Li, Yuning; Leclerc, Mario
• Is Part Of: Materials chemistry frontiers. Volume 4:Number 7(2020)
• Page Start: 2040
• Page End: 2046
• Publication Date: 2020-06-01
• Subjects: Materials science -- Periodicals; Chemistry -- Periodicals; 540
• DOI: 10.1039/d0qm00218f
• Languages: English
• ISSNs: 2052-1529

Abstract

Abstract : Optimized synthesis of fDT-DPP and related 3-fluorothiophene comonomers and application in highly fluorinated polymers obtained via direct heteroarylation polymerization. Abstract : Diketopyrrolopyrrole-based (DPP-based) polymers are a very important class of materials for both organic solar cells (OSCs) and organic field-effect transistors (OFETs). Here we report an optimised synthesis of fluorinated dithienyl-diketopyrrolopyrrole (fDT-DPP) and three new highly fluorinated fDT-DPP-based materials obtained from direct heteroarylation polymerization (DHAP). This study confirms the properties of the fluorine atom in a polymer, activation of the α-position hydrogen on thiophene moieties, decreasing HOMO and LUMO energy, lower bandgaps and modification of the solubility and morphology of the materials.