Anodic hydrazine electrooxidation boosted overall water electrolysis by bifunctional porous nickel phosphide nanotubes on nickel foam. Issue 21 (20th May 2020)

• Record Type: Journal Article
• Authors: Wang, Tian-Jiao; Xu, Guang-Rui; Sun, Hui-Ying; Huang, Hao; Li, Fu-Min; Chen, Pei; Chen, Yu
• Is Part Of: Nanoscale. Volume 12:Issue 21(2020)
• Page Start: 11526
• Page End: 11535
• Publication Date: 2020-05-20
• Subjects: Nanoscience -- Periodicals; Nanotechnology -- Periodicals; 620.505
• DOI: 10.1039/d0nr02196b
• Languages: English
• ISSNs: 2040-3364

Abstract

Abstract : Porous Ni2 P nanotubes on nickel foam are synthesized as bifunctional electrocatalysts for hydrazine electrooxidation boosted overall water electrolysis. Abstract : Water electrolysis is an environmentally friendly and sustainable technique for ultra-pure hydrogen production, while expensive electrode materials and high driving voltage have seriously hindered its commercialization process. Here, Earth-abundant bifunctional porous Ni2 P hollow nanotubes on nickel foam (Ni2 P-HNTs/NF) electrocatalysts are synthesized through a facile self-template method and a phosphating process, which are perfectly combined with the hydrazine electrooxidation reaction (HzOR) boosted water electrolysis. Benefiting from the unique structural characteristic of open-framework and abundant step atoms, Ni2 P-HNTs/NF achieves 10 mA cm −2 at 91 mV ( vs. RHE) for the cathodic hydrogen evolution reaction and 18 mV ( vs. RHE) for the anodic HzOR in a three electrode system, respectively. The corresponding two-electrode hydrazine electrolyzer produces 10 mA cm −2 with a total voltage of only 152 mV for ultra-pure hydrogen production, highlighting a cost-effective and energy-saving water electrolysis mode.