Hysteresis in the gas sorption isotherms of metal–organic cages accompanied by subtle changes in molecular packing. Issue 25 (3rd March 2020)
- Record Type:
- Journal Article
- Title:
- Hysteresis in the gas sorption isotherms of metal–organic cages accompanied by subtle changes in molecular packing. Issue 25 (3rd March 2020)
- Main Title:
- Hysteresis in the gas sorption isotherms of metal–organic cages accompanied by subtle changes in molecular packing
- Authors:
- Craig, Gavin A.
Larpent, Patrick
Urabe, Hinano
Legrand, Alexandre
Bonneau, Mickaele
Kusaka, Shinpei
Furukawa, Shuhei - Abstract:
- Abstract : Cooperative gas uptake in metal–organic cages is tuned using supramolecular chemistry. Abstract : Structural deformation in response to gas sorption is rarely observed for porous molecular solids, when compared to porous framework materials. Here, we describe the effect of chemical modification on the exterior of lantern-type metal–organic cages on the emergence and then disappearance of cooperative gas uptake. The results suggest that supramolecular design of ligands can be used to reveal this behaviour.
- Is Part Of:
- Chemical communications. Volume 56:Issue 25(2020)
- Journal:
- Chemical communications
- Issue:
- Volume 56:Issue 25(2020)
- Issue Display:
- Volume 56, Issue 25 (2020)
- Year:
- 2020
- Volume:
- 56
- Issue:
- 25
- Issue Sort Value:
- 2020-0056-0025-0000
- Page Start:
- 3689
- Page End:
- 3692
- Publication Date:
- 2020-03-03
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/d0cc00932f ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 13868.xml