Enhanced thermomechanical property of a self-healing polymer via self-assembly of a reversibly cross-linkable block copolymer. Issue 22 (24th April 2020)

• Record Type: Journal Article
• Authors: Lee, Hyang Moo; Perumal, Suguna; Kim, Gi Young; Kim, Jin Chul; Kim, Young-Ryul; Kim, Minsoo P.; Ko, Hyunhyup; Rho, Yecheol; Cheong, In Woo
• Is Part Of: Polymer chemistry. Volume 11:Issue 22(2020)
• Page Start: 3701
• Page End: 3708
• Publication Date: 2020-04-24
• Subjects: Polymers -- Periodicals; Macromolecules -- Periodicals; Polymerization -- Periodicals; 547.705
• DOI: 10.1039/d0py00310g
• Languages: English
• ISSNs: 1759-9954

Abstract

Abstract : Introduction of a self-healable block copolymer increases the mechanical property whilst maintaining self-healing efficiency. Abstract : We report the preparation and thermomechanical properties of hetero-nanostructured self-healing polymers (HSPs) bearing a hindered urea bond (HUB) by varying the content of a self-healable block copolymer (BCP). The micellar morphology of the BCP blend in a matrix polymer was studied using transmission electron microscopy and grazing-incidence small-angle X-ray scattering with various organic solvent types and BCP contents. The self-healing efficiency of the HSPs was obtained from single-scratch tests through optical microscopy and atomic force microscopy. To confirm self-healing at the molecular level, the mechanical properties of the cross-cut and healed HSPs were also analyzed using a universal testing machine. Thermomechanical properties associated with HUB were measured by dynamic mechanical analysis and temperature-oscillating rheometry. The results showed that blending the BCP improved the toughness, the hardness, and the modulus up to 21.7, 25.3, and 24.8%, respectively. Moreover, at high temperatures, the temperature range of the rubbery plateau was greatly widened without a noticeable decrease in the self-healing capability.