High redox performance of Y0.5Ba0.5CoO3−δ for thermochemical oxygen production and separation. Issue 4 (19th December 2019)

• Record Type: Journal Article
• Authors: Ezbiri, M.; Reinhart, A.; Huber, B.; Allen, K. M.; Steinfeld, A.; Bulfin, B.; Michalsky, R.
• Is Part Of: Reaction chemistry & engineering. Volume 5:Issue 4(2020)
• Page Start: 685
• Page End: 695
• Publication Date: 2019-12-19
• Subjects: Reaction mechanisms (Chemistry) -- Periodicals; Chemical engineering -- Periodicals; Chemical engineering; Reaction mechanisms (Chemistry); Periodicals; 547.705
• DOI: 10.1039/c9re00430k
• Languages: English
• ISSNs: 2058-9883

Abstract

Abstract : The efficient production and separation of oxygen is essential for numerous energy-intensive industrial applications in the fuel and mineral processing sectors. Abstract : The efficient production and separation of oxygen is essential for numerous energy-intensive industrial applications in the fuel and mineral processing sectors. A thermochemical redox cycle is considered for separating oxygen from atmospheric air and other gas mixtures using solar or waste process heat. Based on electronic structure (DFT) computations Y0.5 Ba0.5 CoO3− δ is selected as a redox material, which surpasses the redox performance of state-of-the-art Cu2 O. The thermochemical oxygen production is experimentally demonstrated by applying a temperature/pressure swing between 573 K at 0.2 bar O2 and 873 K at 1 bar O2 . An energy balance shows the feasibility of using process waste heat from the solar thermochemical CO2 /H2 O splitting cycle and the potential to compete vis-a-vis with cryogenic distillation. Exploratory runs with a packed-bed reactor indicate the potential of both thermochemical oxygen production and separation for scale-up and industrial implementation.