CoS2@N-doped carbon core–shell nanorod array grown on Ni foam for enhanced electrocatalytic water oxidation. Issue 14 (27th March 2020)

• Record Type: Journal Article
• Authors: Pei, Lang; Zhong, Jiasong; Li, Taozhu; Bai, Wangfeng; Wu, Shiting; Yuan, Yongjun; Chen, Yifan; Yu, Zhengtao; Yan, Shicheng; Zou, Zhigang
• Is Part Of: Journal of materials chemistry. Volume 8:Issue 14(2020)
• Page Start: 6795
• Page End: 6803
• Publication Date: 2020-03-27
• Subjects: Materials -- Research -- Periodicals; Chemistry, Analytic -- Periodicals; Environmental sciences -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d0ta00777c
• Languages: English
• ISSNs: 2050-7488

Abstract

Abstract : CoS2 @NGC@NF gives a significant increase of OER catalytic activity due to the injection of electrons from NGC to CoS2, lowering the Fermi level of NGC, facilitating the adsorption and activation of O-containing intermediates. Abstract : Developing a highly efficient and low-cost oxygen-evolution-reaction (OER) electrocatalyst is an important route to overcome the rate-determining step of water splitting. Here, we directly grew a CoS2 nanoarray core with an N-doped graphitic carbon (NGC) shell on Ni foam (NF) to construct a core–shell nanorod array electrode, CoS2 @NGC@NF. The CoS2 core with a high work function (∼5.5 eV) tends to capture electrons from the NGC layer (4.5–5.2 eV) to induce an electron-poor NGC shell with a significant downshift of the carbon Fermi level, facilitating the adsorption of O-containing intermediates and affording decreased activation energy during the OER process. As a result, the three-dimensional NGC encapsulated CoS2 array assembly exhibited excellent electrocatalytic OER activity with a low overpotential of 243 mV at a current density of 10 mA cm −2 and a small Tafel slope of 71 mV dec −1 in 1.0 M KOH. Our findings may suggest that manipulating the interface energetics by the work function difference is a potential route to the design of high-performance OER electrocatalysts.