High-performance transparent conductive pyrolyzed carbon (Py-C) ultrathin film. Issue 27 (17th June 2020)

• Record Type: Journal Article
• Authors: Pal, Monalisa; Lee, Gilwoon; Giri, Anupam; Thiyagarajan, Kaliannan; Baek, Kangkyun; Kumar, Manish; Jeong, Unyong
• Is Part Of: Journal of materials chemistry. Volume 8:Issue 27(2020)
• Page Start: 9243
• Page End: 9251
• Publication Date: 2020-06-17
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/d0tc01936d
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : This study proposes a substrate independent, large-area synthesis strategy for pyrolyzed carbon (Py-C) ultrathin films directly on various target substrates. The Py-C film has opto-electro-mechanical properties comparable to those of graphene. We demonstrated a highly flexible pixelated display composed of the Py-C film. The Py-C film showed remarkable performance as a protective layer against Cu oxidation and the chemical etching of ITO. Abstract : Pyrolyzed carbon (Py-C) film, a member of graphene family, has not been paid significant attention despite its potential advantages in synthesis procedure and opto-electro-mechanical properties. This academic indifference is due to the lack of a low-cost synthesis method for Py-C ultrathin films whose properties are comparable to those of graphene. In this study, we proposed the direct synthesis of Py-C ultrathin films on various target substrates. We produced a hydrogenated amorphous carbon (a-C:H) ultrathin film in a microwave oven and used it as a transferable precursor film for conversion into the Py-C ultrathin film. The thickness of the Py-C ultrathin film was controlled in the range of 0.7–12 nm. The Py-C ultrathin film has opto-electro-mechanical properties comparable to those of graphene, work function (4.57 eV) similar to that of graphene, high transparency with a relatively low sheet resistance (83% at 1.1 kΩ sq −1 ), excellent flexibility, stable electrical resistance upon folding, anti-oxidation, and chemical protection. This Py-C ultrathin film is expected to find various practical applications as an alternative to graphene. As an example, we demonstrated a highly flexible pixelated display fabricated using the Py-C ultrathin film as an electrode for alternating current electroluminescent (ACEL) devices.